Following Dhirubhai Ambani's passing in July 2002, Mukesh Ambani assumed the role of chairman at Reliance.

Mukesh Ambani has an estimated net worth of $80.7 billion.

Mukesh Ambani decided to cap his yearly salary at Rs 15 crore in 2008–09. The following year, he received the same amount of money.

Reliance Industries Limited's most recent annual report states that Mukesh Ambani, the richest man in Asia and the company's chairman and managing director, has not received any compensation from the enterprise for the fourth year in a row.

In addition to retirement benefits, he received 'nil' in salary, allowances, and perks in 2023–2024, according to the company's most recent annual report.

Mukesh Ambani's wife Nita Ambani and their kids Akash, Isha, and Anant got a commission and a sitting fee for being on the board of the company in the most recent fiscal year.

In June 2020, Ambani voluntarily decided not to receive his salary for the 2020–21 fiscal year.

Following the global COVID-19 pandemic in 2020–21, Mukesh Ambani decided not to receive compensation until Reliance and other companies he oversaw had recovered financially.

Isha, Akash, and Anant Ambani each got a sitting fee of Rs 4 lakh, in addition to a commission of Rs 97 lakh. It follows that Reliance did not pay any of the Ambani family's workers a salary in the preceding year.